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16.
The reaction of ethyne with bromine water gives
  • A.
    cis-1,2-dibromoethene
  • B.
    trans-1,2-dibromoethene
  • C.
    1,1,2,2-tetrabromoethane
  • D.
    none of these
  • Answer
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Answer : [B]
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17.
The reduction of 4-octyne with H2 in the presence of Pd/CaCO3- quinoline gives
  • A.
    trans-4-octene
  • B.
    cis-4-octene
  • C.
    a mixture of cis- and trans-4-octene
  • D.
    a completely reduced product C8H18
  • Answer
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Answer : [B]
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18.
On halogenation, an alkane C5H12 gives only one monohalogenated product. The alkane is
  • A.
    n-pentane
  • B.
    2-methylbutane
  • C.
    2,2-dimethylpropane
  • D.
    cyclopentane
  • Answer
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Answer : [C]
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19.
The angle strains at the CH2 groups in cyclopropane (I), cyclobutane (II) , cyclopentane (III) and cyclohexane (IV) follow the order
  • A.
    IV > III > II > I
  • B.
    I > II > III > IV
  • C.
    II > I > IV > III
  • D.
    III > II > I > IV
  • Answer
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Answer : [B]
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20.
The order of reactivity of F, Cl, Br and I in substitution reactions is
  • A.
    F > Cl > Br > I
  • B.
    Cl > Br > I > F
  • C.
    I > Br > Cl > F
  • D.
    Cl = Br > I > F
  • Answer
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Answer : [A]
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