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11.
In the reaction of optically active 2-bromo-octane with sodium hydroxide to give 2-octanol, there is
  • A.
    retention of configuration
  • B.
    inversion of configuration
  • C.
    retention and inversion of configuration in equal amounts of the product
  • D.
    no reaction
  • Answer
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Answer : [B]
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12.
Which of the following alkyl halides is unreactive in an SN2 reaction?
  • A.
    Primary
  • B.
    Secondary
  • C.
    Tertiary
  • D.
    Methyl chloride
  • Answer
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Answer : [C]
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13.
The maximum yield of chloromethane (methyl chloride) by the chlorination of methane is obtained by
  • A.
    using a considerable excess of methane in the reaction mixture
  • B.
    using a large excess of chlorine in the reaction mixture
  • C.
    using a 1 : 1 mixture of methane and chlorine
  • D.
    carrying out the chlorination in the presence of UV light
  • Answer
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Answer : [A]
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14.
The major product obtained in the reaction of propyl benzene with chlorine in the presence of UV radiation is
  • A.
    1-chloro-1-phenylpropane
  • B.
    2-chloro-1-phenylpropane
  • C.
    3-chloro-1-phenylpropane
  • D.
    none of these
  • Answer
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Answer : [A]
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15.
The halogen derivatives of alkenes are known as
  • A.
    alkyl halides
  • B.
    alkenyl halides
  • C.
    alkynyl halides
  • D.
    aryl halides
  • Answer
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Answer : [B]
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