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21.
Anhydrous magnesium chloride can be prepared by heating MgCl2.6H2O
  • A.
    with concentrated HCl
  • B.
    in an atmosphere of nitrogen
  • C.
    in a current of dry HCl gas
  • D.
    in an atmosphere of hydrogen
  • Answer
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Answer : [C]
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22.
In the Solvay process
  • A.
    an ammoniacal brine solution is carbonated with CO2, forming NaHCO3 which on decomposition at 150oC produces Na2CO3
  • B.
    a sodium amalgam reacts with water to produce NaOH which gives Na2CO3 on reacting with CO2
  • C.
    a brine solution is made to react with BaCO3 to produce Na2CO3
  • D.
    brine is carbonated with CO2 forming NaHCO3 which on decomposition at 150oC produces Na2CO3
  • Answer
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Answer : [C]
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23.
When a saturated solution of magnesium sulphate is treated with NH4Cl and NH3, followed by the addition of disodium hydrogen phosphate, a white precipitate of
  • A.
    Mg2P2O7
  • B.
    Mg3(PO4)2
  • C.
    Mg(NH4)PO4
  • D.
    Mg(NH4)HPO4
  • Answer
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Answer : [C]
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24.
The order of the solubility of the sulphates of alkaline earth metals in water is
  • A.
    Be > Mg > Ca > Sr > Ba
  • B.
    Mg > Be >> Ba > Ca > Sr
  • C.
    Be > Ca > Mg > Ba >> Sr
  • D.
    Mg > Ca > Ba >> Be > Sr
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Answer : [A]
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25.
The solubility of the fluorides and hydroxides of alkaline earth metals increases on descending the group because the
  • A.
    lattice energy of the compounds increases more rapidly than the hydration energy
  • B.
    lattice energy of the compounds decreases more rapidly than the hydration energy
  • C.
    size of the metals decreases on descending the group
  • D.
    ionization energy of the metals increases on descending the group
  • Answer
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Answer : [B]
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