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1.
The hydrogen molecule is not very reactive under normal conditions because
  • A.
    hydrogen has a large number of isotopes
  • B.
    the corresponding △So value is very low
  • C.
    the bond dissociation energy of the hydrogen molecule is high
  • D.
    the hydrogen molecule has a low activation energy
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Answer : [C]
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2.
The ionization constant of protium in water (H2O⇌H+ + OH-) is 1.0 x 10-14 and that in heavy water (D2O⇌ D+ + OD-) is 3.0 x 10-15.H2O dissociates about
  • A.
    three times as much as D2O does
  • B.
    thirty times as much as D2O does.
  • C.
    0.3 times as much as D2O does
  • D.
    300 times as much as D2O does.
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Answer : [A]
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3.
The order of the heats of fusion of T2, D2 and H2 is
  • A.
    T2 > D2 > H2
  • B.
    H2 > T2 > D2
  • C.
    D2 > T2 > H2
  • D.
    D2 = T2 > H2
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Answer : [A]
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4.
The higher density of water than that of ice is due to
  • A.
    dipole-dipole interaction
  • B.
    dipole–induced dipole interaction
  • C.
    hydrogen bonding
  • D.
    all of these
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Answer : [C]
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5.
In parahydrogen, the electron spins are in the
  • A.
    same direction but the proton spins are in opposite directions
  • B.
    opposite directions but the proton spins are in the same direction
  • C.
    same direction as the proton spins
  • D.
    opposite direction to the proton spins
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Answer : [D]
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