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6.
Which of the following statements is incorrect for graphite?
  • A.
    Its density is lower than that of diamond.
  • B.
    It has a layered structure and the bonding between the layers is very weak.
  • C.
    Its layers are very tightly packed, almost without any space between them
  • D.
    It cleaves easily between the layers which accounts for the remarkable softness of the crystals.
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Answer : [C]
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7.
Which of the following statements is correct?
  • A.
    Graphite is thermodynamically more stable than diamond
  • B.
    Diamond is thermodynamically more stable than graphite
  • C.
    Graphite has such a high thermodynamical stability that diamond spontaneously changes into graphite in ordinary conditions
  • D.
    Graphite and diamond have equal thermodynamic stability.
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Answer : [A]
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8.
Among the following, the tendency for catenation decreases in the order
  • A.
    C > Si > Ge = Sn > Pb
  • B.
    Si > C > Ge = Sn > Pb
  • C.
    C > Ge > Sn > Si > Pb
  • D.
    C > Pb > Sn > Ge > Si
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Answer : [A]
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9.
In the equilibrium C(s, diamond)⇌ C(s, graphite) + heat (density of diamond and graphite are 3.5 and 2.3 g/cm3 respectively), the equilibrium will be shifted to the left at
  • A.
    low temperature and very high pressure
  • B.
    high temperature and low pressure
  • C.
    high temperature and very high pressure
  • D.
    low temperature and low pressure
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Answer : [C]
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10.
In the carbon family the melting points of the elements decrease on descending the group because the interatomic bonds become
  • A.
    stronger as the size of the atom increases
  • B.
    weaker as the size of the atom decreases
  • C.
    stronger as the size of the atom decreases
  • D.
    weaker as the size of the atom increases
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Answer : [D]
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